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Phase diagram of R-Fe-Co pseudoternary system with R <= 33.3% (mole fraction, R = Sm0.5Dy0.5)

Transactions of Nonferrous Metals Society of China

Phase equilibria of the R-Fe-Co pseudoternary system with R less than or equal to 33.3% ( mole fraction, R = Sm0.5Dy0.5) were determined in an isothermal section at 1073 K and a vertical section of RFe2-RCo2 by using OM, X-ray diffractometer, EP-MA DTA techniques. There are seven intermetallic phases: (Sm, Dy) (Fe, Co)(2), (Sm, Dy) (Fe, Co)(3), (Sm, Dy)(6) (Fe, Co)(23), (Sm, Dy)(2) (Fe, Co)(7), (Sm, Dy) (Fe, Co)(5), Th2Ni17-type and Th2Zn17-type (Sm, Dy)(2)(Fe, Co)(17). The (Sm, Dy)(6)(Fe, Co)(23) phase dissolves 36% Co(mole fraction) at 1073 K. However, the (Sm, Dy)(2)(Fe, Co)(7) phase in R-2(Fe1-xCox)(7) alloys dissolves about 19% Fe(mole fraction) at 1073 K.

关键词: rare earth-iron-cobalt;phase diagram;structure;compounds;sm-co;magnetic-properties;binary-system;magnetostriction

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